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=

NEET 29 v/;k;okj YEARS

2

mc

H2O

lkWYo~M isij

jlk;u foKku CH2

2

mc

E=

1993&2021 is i j CH 2

C2H8

CP Publication

Model Test Paper

Download eCareerPoint App

Years AIPMT CHAPTERWISE SOLVED PAPERS

Information contained in this work has been obtained by Career Point from sources believed to be reliable. However, neither Career Point nor its authors guarantee the accuracy or completeness of any information published herein, and neither Career Point nor its authors shall be responsible for any errors, omissions, or damages arising out of use of this information. This work is published with the understanding that Career Point and its authors are supplying information but are not attempting to render any professional services. If such services are required, the assistance of an appropriate professional should be sought.

CP Tower, Road No.-1, IPIA, Kota (Raj.) Email : [email protected]

No part of this publication may be reproduced or distributed in any form or by any means, electronic, mechanical, photocopying, recording, or otherwise or stored in a database or retrieval system without the prior written permission of the Publishers. The program listings (if any) may be entered, stored and executed in a computer system, but they may not be reproduced for publication.

This edition can be exported from India only by the publisher.

Published by Career Point Ltd. CP Tower, Road No.-1, IPIA, Kota (Raj.) Email : [email protected] Book No. : CPP-171

Preface

AIPMT (NEET)

1993

2021 Concept

`

Content Development team

Career Point Ltd.

.

CONTENTS Chapter 1. Answers & Solutions

1-7 4

Answers & Solutions

8-15 12

Answers & Solutions

16-24 21

Answers & Solutions

25-33 30

Answers & Solutions

34-39 37

Answers & Solutions

40-58 49

Answers & Solutions

59-76 68

Answers & Solutions

77-82 80

Answers & Solutions

83-90 87

Answers & Solutions

91-97 95

Answers & Solutions

98-107 103

Answers & Solutions

108-118 114

Answers & Solutions

119-127 124

Answers & Solutions

128-132 131

2.

3.

4.

5

6.

7.

8.

9.

10.

11.

12.

13

14.

Page No.

`

Chapter 15.

sAnswers & Solutions

`

16.

17.

18.

Answers & Solutions

Answers & Solutions

143-153 149

d & fAnswers & Solutions

154-162 159

Answers & Solutions

163-176 170

Answers & Solutions

177-195 188

Answers & Solutions

196-208 203

Answers & Solutions

209-212 211

(X) Answers & Solutions

213-219 217

Answers & Solutions

220-245 235

Answers & Solutions

246-259 254

Answers & Solutions

260-267 264

Answers & Solutions

268-272 271

Answers & Solutions

273-280 278

Model Test Papers Answers & Solutions

281-288 286

p-

20.

21.

22.

24.

25.

26.

27.

28.

29. ,,

133-139 137 140-142 142

19.

23.

Page No.

Chapter

1 1.

4.4 gm CO2 (A) 1.2 × 1023 (C) 6 × 1023

(B) 6 × 1022 (D) 12 × 1023

: [1993]

9.

H2

O2

8 : 1 ?

(A) 1 : 1

(B) 2 : 1

10. 10 5 B

2.

11 5 B

10 5 B

11 5 B

:

(A) 19/81 (C) 15/16

[1994] 11.

(B) 20/53 (D) 10/11

3. (29.2 – 20.2)(1.79 10 5 ) 1.39 (A) 3 (B) 1 (C) 4 4.

9.85 CO2 (A) 2.24 L (C) 0.84 L

`

10.81

[1994] (D) 2

Se

(A) 1.568 × 10 (C) 15.68

(Zn = 65, S = 32, O = 16 and H = 1) (A) 33.65% (B) 32.56% (C) 23.65% (D) 22.65% 6.

[1995]

[1995]

8.

161 0.0161 (A) 3,3,3

(C) 3

(D) 4

(C) 3,2,3

: [1998] (D) 3,4,4

1.61

(B) 3,4,3

(B) 2 gm H2 (D) 16 gm O2

14.

: [2004] (A) (B) (C) (D)

67, 200

(B) 2

: [2001] 3 (B) 1.568 × 10 (D) 2.136 × 104 : [2002]

(A) 7 gm N2 (C) 16 gm NO2

0.33%

(A) 1

4

13.

C60H22 [1995] (A) 1.2 × 10–20 gram (B) 1.4 × 10–21 gram (C) 5.025 × 1023 gram (D) 6.023 × 1023 gram

7.

[2000]

0.5%

(B) 4.2 NA (D) 1.6 NA

(white Vitriol - ZnSO4.7H2O)

BaSO3

(virus particle) 6.02 × 10–2 cc/gm 7 A 10 A NA = 6.02 × 1023 [2001] (A) 15.4 kg/mol (B) 1.54 × 104 kg/mol (C) 3.08 × 104 kg/mol (D) 3.08 × 103 kg/mol

[1994] (A) 2.1 NA (C) 3.2 NA

[1999] (D) 1 : 2

: (B) 1.12 L (D) 0.56 L

12.

4.2g N3–

5.

(C) 4 : 1

15. : (A) 0.5 g (B) 10 g (C) (D)

[2004]

15 5

2

TOPIC- WISE NEET (AIPMT)

16.

270 kg

23.

Questions with Solutions

25.3 g

, Na2CO3 250 mL

(

)

:

= 27) : (B) 540 kg (D) 180 kg

(Al (A) 270 kg (C) 90 kg 17.

= 106 g mol–1) [2010] (Na2CO3 (A) 0.955 M and 1.910 M (B) 1.910 M and 0.955 M (C) 1.90 M and 1.910 M (D) 0.477 and 0.477 M

KI KMnO4 (A) 1 (C) 5

18.

: (B) 2 (D) 1/5

[2005] 24.

X 200

X : 90% X : 8.0% 202 X : 2.0%

(A) 6.026 × 1022 (C) 3.600 × 1023

199

`

X

: (A) 200amu (C) 202 amu 19.

1

[2007]

(C3H8)

(

26.

(0ºC

1 atm

6.5g PbO

(B) 7 L (D) 5 L

(

AgCl : (A) 0.001 (C) 0.003 27.

? (B) 0.044 (D) 0.011 = 1 g cm–3)

28.

22.4

H2(g)

11.2

Cl2(g)

C, H, 9.67% [2008] (B) CH3O (D) CHO

1.0 g

: (B) 2 (D) 1.5

[2014] HCl(g) HCl(g)

0.56g O2 ?

[2014]

(Mg = 24; O = 16) (A) Mg, 0.16g (B) O2, 0.16 g (C) Mg, 0.44 g (D) O2, 0.28 g

22.

(A) CH4O (C) CH2O

[2013] (B) 0.002 (D) 0.01

HCl(g) (A) 1 HCl(g) (C) 0.5 HCl(g)

[2008]

[2008] (B) 9.0 × 10–23 cm3 (A) 5.5 × 10–23 cm3 (C) 6.023 × 10–23 cm3 (D) 3.0 × 10–23 cm3

38.71%

(III) AgNO3

3.2g HCl

(II) (A) 0.029 (C) 0.333 21.

(B) 44 g CO2 (D) 8 g H2

0.01 100 mL

) [2008]

(A) 10 L (C) 6 L

? [2011] (A) 64 g SO2 (C) 48 g O3

) 0ºC

0.1 mol ? (NA = 6.02 × 1023 mol–1) [2010] (B) 1.806 × 1023 (D) 1.800 × 1022

25.

(B) 201 amu (D) 199 amu

L

1 atm

20.

, CO32–

Na+

[2005]

H2

29.

1 : 4 (w/w) ? (A) 1 : 4 (C) 16 : 1

O2 [2015]

(B) 4 : 1 (D) 2 : 1

3 30.

:

34.

(B) 18

(A) 18 18

(C)

[2015]

XY2

(D) 1.8

[2015]

(A)

10 g

X

Y

(B) 60, 40 (D) 30, 20 20

(A) 30

(B) 40

(C) 10

[2019] (D) 20

36. ?

20.0 g 8.0 g

(A) 60 33.

XY2

9g

35.

(C)

32.

0.1 X3Y2

(A) 40, 30 (C) 20, 30

(B) (D)

Y

[2016]

6.022 × 1020 mol–1 :

X3Y2

0.05

NA, 6.022 × 1023 mol–1

31.

X

(B) 84

(C) 75

50 mL, 16.9% AgNO3

? [2015] (D) 96 50 mL,

[2020]

(A) Mg(s) (B) O2(g)

1 g [Mg 1 g [O

= 24] = 16]

(C) Li (s)

1 g [Li

= 7]

(D) Ag(s)

1 g [Ag

37.

= 108] 78% (

5.8% NaCl ? [2015] (Ag = 107.3, N = 14, O = 16, Na = 23, Cl = 35.5) (A) 7g (B) 14g (C) 28g (D) 3.5 g

) :[

C = 12, H = 1] (A) CH4 (B) CH

(C) CH2

[2021] (D) CH3

4

TOPIC- WISE NEET (AIPMT)

Questions with Solutions

ANSWERS 1. (A)

2. (A)

3. (A)

4. (D)

5. (D)

6. (B)

7. (D)

8. (A)

9. (D)

10. (B)

11. (A)

12. (A)

13. (B)

14. (D)

15. (C)

16. (C)

17. (A)

18. (A)

19. (D)

20. (A)

21. (D)

22. (B)

23. (B)

24. (B)

25. (D)

26. (A)

27. (A)

28. (A)

29. (B)

30. (B)

31. (D)

32. (B)

33. (A)

34. (A)

35. (A)

36. (C)

37. (D)

SOLUTIONS 1.

2.

44 gm. CO2 = 1 mol. CO2 4.4 gm. CO2 = 0.1 mol. of CO2 CO2 = 6.0 × 1023 0.1 CO2 = 6.0 × 1022 No of O-atoms in 1 CO2 molecule are 2 = 2 × 6 × 1022 No of O-atoms in 4.4 gm CO2 = 2 × 6 × 1022 = 12 × 1022 = 1.2 × 1023 5B

7. = = 8.

100

67200 0.33 = 4. 100 56

161 0.0161

1.61

11

x:y 10x 11y 10.81 = x y 10.81 x + 10.81 y = 10x + 11y 0.81x = 0.19y x 19 = y 81

9.

H2 H2

O2

2 gm

O2

8:1 8 × 2 : 1 × 32

10.

BaCO 3 197.33g

3.

BaO + CO2 22.4lit

1937.33 g BaCO3

N7 = 2, 5 N–3 = (5 × 3) + 1 = 16

5.

ZnSO4 7H2O = 65 + 32 + 4 × 16 + 7 (2 × 1 + 16) = 287

6.

= =

11.

= 22.4 lit CO2 22.4 × 9.85lit CO2 197.33 = 1.118 lit. 1.12 lit

9.85g BaCO3

4.

=

= r2l = 3.14 × (7 × 10–8)2 × (10 × 10–8) = 3.14 × 49 × 10–16 × 10–7 = 153.86 × 10–23 c.c. =

H122

=

842 23

6.023 10 = 1.4 × 10–21 gm.

32 gm

153.86 10 –21 6.02 10 – 2

gm

153.86 10 –21 × 6.02 × 1023 6.02 = 15.4 kg/mol.

=

5 12.

0.5% Se

17.

78.4 gm Se

OH –

7

6

KMnO 4

K 2 MnO 4

Mn KI,

100 × 78.4 = 156.8 × 102 m 0.5 = 1.568 × 104 gm

=

KMnO4 18.

13.

=

× NA

A =

7 NA = 0.25 NA 28 2 NA = NA (2) 2 16 (3) NA = 0.347 NA 46 16 (4) NA = 0.5 NA 32 (1)

A =

A( x i ) xi 200 0.9 199(0.08) 1

202(0.02)

A = 200 a.m.u. 19.

C3H8 + 5O2 3CO2 + 4H2O 1 mol 5 × 22.4 ltr 22.4 ltr 5 × 22.4 ltr 1 ltr 5 ltr

20.

PbO 223

14.

15. 0.5 × 3.023 × 1023 2 10 (B) × 6.023 × 1023 32 15 (C) × 6.023 × 1023 22.4 5 (D) × 6.023 × 1023 22.4

PbO

(A)

16.

=

0.5 ×2 223 )

= 0.058 ( eq. of HCl =

3.2 × 1 = 0.08767 36.5 = PbCl2

PbO

0.058 = n × z 0.058 n= = 0.029 2

27 = 9. 3 12 = = 3. 4

Al

+ 2HCl PbCl2 + H2O + 73 278 gm 6.5 gm 3.2 gm

=

C

21. 18 cm 3

C

270 10 3 = 3×103 9 = 30 × 103

C

=

6.023 10

23

= 3 × 10–23 cm3

=

Al

30 × 103 =

22.

C

38.71

O

51.62

H

9.67

(gm )

3 = 3 × 30 × 103 = 90 × 103 gm. = 90 kg.

38.71 = 3.226 12 51.62 = 3.226 16 9.67 = 9. 67 1 = CH3O

1 1 3

6

TOPIC- WISE NEET (AIPMT)

23.

(M) =

29.

wt 1000 mol.wt. vol(ml) 25.3 1000 × 106 250 = 0.955 mol/L of Na2 CO3 Na2CO3 2Na+ + CO3–2

=

0.1 × 3 × 6.023 × 1023 = 1.806 × 1023

25. 26.

27.

=

H2 + Cl2 2HCl 22.4 n H2 = = 1 ; n Cl2 22.4 L.R. H2 Cl2 1 1 1 2 1 1 2 Cl2, L.R. n HCl n Cl2

2

:

O2

1

:

4

1 2

:

4 32

:

1 8 4:1

18 g H2O = 1 mol H2O 6.02 × 1023

H2O

18 mol H2O , 18 × 6.02 × 1023 H2O 1.8 g H2O, 0.1 mol H2O = 0.1 × 6.02 × 1023 = 6.02 × 1022 31. NA : 6.023 × 1023

12g

11.2 22.4

1 2

12 6.022 10 20 6.023 10 23

32.

MgCO3

MgO + CO2

84 g MgCO3

40g MgO

84 8 = 16.8 g MgCO3 40

8g

1 = 1 mol. 2

2Mg + O2 2MgO 1 ~ 0.56 nMg = 0.042 & n O 2 = = 0.0175 24 32 L.R. Mg O2 0.042 0.0175 = 0.021 = 0.0175 2 1 O2, LR Mg nMg, reacted = 0.0175 × 2 = 0.035 nMg, unreacted = 0.007 nMg, remained = 0.007 × 27 = 0.16g

6.022 × 1020

12g

1

nHCl = 2 × 28.

30.

8 NA = 4NA 2

AgNO3 + [Cr(H2O)4Cl2]Cl AgCl = MV(lit) 100 = 0.01 × = 0.001 1000

H2

1 2 4 :1 8

[Na+] = 2 × 0.955 = 1.910 M [CO3–2] = 0.955 M 24.

Questions with Solutions

% purity =

33.

16.8 × 100 = 84% 20

AgNO3

(M) =

16.9 10 = 1.0 M 169.3

5.8 × 10 = 0.9914M 58.5 AgCl + NaNO3 AgNO3 + NaCl 0.99 M 50 0.99 50 n= 1000 1000 =

NaCl

~ 0.05 AgCl AgCl

~ 0.05 = 0.05 = 0.05 × 142.5 = 7 g

7 34.

XY2 0.1

36.

= 10 g

w

=

× NA ×

= ? = 100 g mol wt X3Y2 0.05 1

=9g 9 =?= 180g mol.wt 0.05

XY2 a + 2b = 100 X3Y2 3a + 2b = 180 (2) – (1) 2a = 80 a = 40 b = 30

(1) …(2)

(A)

1 NA 1 7

(B)

1 NA 1 108

(C)

1 NA 1 24

(D)

1 NA 2 32

37. C

78%

H

22%

CH3 35.

N2 + 3H2 2NH3 =? 20 2× H2 = 3 × NH3 2 × x = 3 × 20 x = 30

78 12 22 1

6.5 22

6.5 1 6.5 22 3.38 3 6.5

Chapter

2 7.

1.

( (A) 1 : 2 : 3

0°C [1993]

(B) 1 :

(A) (B) (C) (D) 2.

300 K 2gm

2 :

3

(C)

2 :

3 :

8/

(D)

2 :

8/

: 3

27ºC

(A) (C) 9.

1 atm

(B) (D)

50 ml 20

40 ml

d

:

0.75d : [1993] (A) 400K (B) 800K (C) 600K (D) 450K 4. 2 mole litre–1 [1993]

2 atm :

[1994]

(A) 12 (C) 64

(B) 8 (D) 32

10. :

[1995]

(A)

(A) STP V = 22.4 (B) (C) T = 12K (D) O2

[1994]

[1994]

0.75 atm

: [1993] (A) 900K (B) 800K (C) 600K (D) 450K

5.

:

8.

1 atm

3.

)

(B) Tc (C) (D)

23ºC

Pc Tc Pc

751 mm Hg 11.

(23ºC O2 (A) 21mm Hg (C) 0.96 atm 6.

S.T.P. (A) (B) (C) (D)

0.50 mol H2

V.P. 21 mm Hg ) [1993] (B) 751mm Hg (D) 1.02 atm 1.0

: HCl [1993]

21% (A) 2.10 (C) 0.186 12.

[1995] (B) 0.0093 (D) 0.21 :

(A) (B) (C) (D)

[1995]

9 13. (A) 550K (C) 350K 14.

S.T.P.

1 atm 3 atm

[2006] 2 atm 4 atm

H2SO4 ? (B) 6.5 gm (D) 0.065 gm

?

22.

23.

:

[1998] (B) 1.00 A (D) 1.15 A

400ml 600

:

[1999] (B) Zero (D) 9 lit.atm.

500 3

666.6ml

19. (

(A) 4 : 1 (C) 8 : 1

(A) (B) (C) (D)

, , , ,

[2002]

1 : 4

[2005]

[2008] (A) (B) (C) (D)

(B) CO2, N2O (D) H2 O2 H2 : O2 : (B) 1 : 8 (D) 1 : 2

20

26.

) [1999]

(A) NO2, CO2 (C) NO2, N2O

8:1

(R = 2 cal/mol K) : (B) Zero (D) 9.2

20ºC 400mm Hg 120 mm Hg : (A) 0.549 (B) 0.478 (C) 0.200 (D) 0.786

[1999]

20.

(A) 92.1 (C) 4

25.

(B) 400 (D) 50

(A) 200 (C) 600

2

[2002] 300 K

E (A) 163.7cal (C) 1381.1cal

2

(B) KE > KE2 (D)

24.

17.

18.

27ºC

x60º

(A) 0.575 A (C) 2.00 A

N2 [2001]

(A) KE1 = KE2 (C) KE1 < KE2

[1996] (B) 6.17 × 10–21 (D) 7.16 × 10–21

1.00 A

CO :

25ºC (A) 61.7 × 10–21 (C) 6.17 × 10–20

KE [2000]

(A) KE CO < KE N2 (B) KE CO > KE N2 (C) KE CO = KE N2 (D)

[1996]

:

16.

N2

224 ml

(A) 0.65 gm (C) 65 gm 15.

CO

21. ? (B) 450K (D) 250K

27. [2000]

(

) ? [2011]

(A) 1.4 (C) 2.8

(B) 2.0 (D) 4.0

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